My husband uses his Outlander PHEV for his 10 mile round trip daily commute. We haven't done a proper road trip yet, but we do take it to visit friends and family on the weekends. So far he loves it. The only complaint is that he added a roof rack (Dealer installed, Thule) and it whistles. He loves the cruise control. He's not a fan of leather seats (hot in summer), but he is dealing with them because a sunroof was very important to him.
To Pushmi-Pullyu's point on electric range, he went with the Outlander (22 miles EV) over the Pacifica (33 miles EV) because all wheel drive was important to him.
Comparison:
https://www.fueleconomy.gov/feg/Find.do?action=sbs&id=39830&id=39483
The Outlander replaced our 2012 CR-V. It has fewer cup holders and cubbies, which we miss. The CR-V was more of a mom-mobile. The rear cargo area is on par. I can't comment on driver headroom - neither of us are close to 6 feet tall. We have fit 4 adults and 1 kid in a booster in the Outlander several times, but the other 2 adults were always doting grandparents who were OK with snuggling their grandbaby. The rear seat behind the driver is narrower than the rear seat behind the passenger and the buckles overlap so there's quite a dance to get everyone buckled, but it's doable for the drive to/from the airport, restaurant, beach, etc.
My only other rambling complaint is that the rear floor is not smooth. There's a weird gulley around the rear floormats which I'm certain will collect goldfish crackers and I'll need the crevice attachment to clean out. Like I said, the CR-V was more of a mom-mobile.