RPM of any component is of no concern to the user of the Clarity. It is fine to drive up to top speed, the low top speed of 101 is easily covered by the engine (only needs like 70 hp on flat ground to go that fast).
Electric motors can't over-rev. The motor in the Clarity has a max speed set by the frequency put out by the motor controller and physical design of motor, and that also limits the top speed of the car. It doesn't have valves or pistons that are physically limited by movements and inertia at high RPM. They are less efficient at certain RPMs which is why the car has different modes of operation.
If battery gets hot hill climbing the car will start the engine for assistance. Going up a long steep mountain pass at 80 mph the car only went 5 mins or less before the engine started even though I was under the blue power arc indicator on dash.
The gas engine can drive the wheels mechanically (direct overdrive gear) or electrically (eCVT, electronic variator). If you go to the powerflow display, if the gear lights up between the engine and battery/between wheels the clutch is engaged meaning engine is physically driving wheels (most efficient mode at higher speeds).
In eCVT mode the RPM of gas engine is selected based on load (which might be charging the battery so can be high RPM at at 0 mph, aka "angry bees" in rare cases). In mechanical overdrive, engine RPM is based on wheel speed, but this mode is only selected by computer in situations where it is safe and more efficient to do so.
Bottom line is the car worries about protecting itself, you just have to drive. If you dramatically exceed design constraints of car, you could experience sudden power loss (overheating battery, motor, inverter, etc). In practice I haven't seen this yet even driving 80 mph for most of a day. The engine was able to cover slack from battery in my hill climb case.
Did a few edits to add some additional info.