Honestly believe you are overthinking this. I would definitely start by standing the charger off the brick an inch or so with a rubber grommet or 4, and a couple of longer screws/bolts. Then build a simple awning 1-2ft wide that sticks out a foot or so and tack it up. You could use shade fabric and 1 piece of 1x2x8 a staple gun and two small hinges to make the whole thing. $10-15 and a kinda fun project for the weekend. If it solves the problem you can dream up something fancier using more robust materials. Use a subdued fabric hang it over the lip maybe 6 to 8 inches. Hinges between the 1x2 strip on the wall and the fabric frame to let it flop down, two short sticks on the side frame to set your angle. Mitre saw or sabre saw to cut the square && angles. Some longish nails screws or corner frames to make the square.
I've seen one of those big wall thermometers at poolside hit well past the 160F final graduation mark (Okay Im in PHX none the less...). We moved it on the same wall about 8 feet and under the porch overhang away from the brutal sun and the afternoon max readings dropped to the 120+ range (With actual temps over 110. It was pretty high up in the porch overhang. it didn't dawn on me to stand it off the stucco wall, I bet that would have gotten me much closer to actual.
Poor mans option:I think standoffs were a great idea and cheap ACE hardware or something. Then just drape a white hand towel over it.
Suggest: Get one of those red beam thermometer guns at harbor freight. Test the temperature at the worst time, drape a towel in the AM lift and test at the same time. Direct sunlight can make metal REALLY hot. The difference between grabbing the 14mm wrench on the sunny side of my driveway for 5 minutes, and the same wrench under the car 5 min is a blister.
Good Luck,