Yesterday, I looked at this...
Outbound, I was in EV mode, and the voltage was always 14.4. I switched to HV for the 2nd half of the trip, and the voltage was always 12.4.
Home-bound, I started out in HV mode, and the battery voltage was always 14.4. I switched to EV half-way home, and the voltage was always 14.4.
The Outbound leg was during the day, and the Home-bound leg was at night (headlights on).
I believe the moral is that the Clarity charges the 12V battery when it needs to be charged. This is indicated by the 14.4V level. In my case, during the day in HV mode it did not need to be charged so it was 12.4V. At night (with the headlights) in HV mode it needed to be charged, so it was 14.4.
My guess is that you will likely experience both charging and non-charging conditions in BOTH EV and HV modes. Although during my experiment, I never saw non-charging in EV mode, I believe it will occur sometimes.
Thanks MrFixit for taking the time and effort to test your Clarity and respond with your results. I want to reach the same conclusion, that the Clarity is making a decision whether the battery needs charging or not, whether HV or EV mode, and applies either the high level charging in the 14.5v range, or the low level (no charge?) 12.6v battery level.
So far, though, I haven't been able to replicate the decision behavior that your reported on my own Clarity. I've made a bunch of drives the last few weeks, in EV mode with battery level prior to startup as high as 12.53v, and the car has invariably held the battery level at the higher 14.5-6v level throughout the drives. In contrast, I've done a number of tests in HV mode with initial battery levels as low as 12.34v, but it has always provided a sustained lower battery voltage of around 12.6v level. So far, it has never applied the higher voltage for more than a couple of minutes, if at all, and always stays at that low level for the rest of the drive.
Either the Clarity has a different standard of when it "needs charging" for EV and for HV modes, there is another variable involved, or perhaps I have a defect in my vehicle. I think my next move is to let the battery voltage to decline, without charges, as much as I can, to see if I can ever get it low enough to trigger the HV higher charge voltage to be applied.
I wouldn't really care about the HV charging concern, since I use it so infrequently, except that it could leave the car more vulnerable to discharge when we drive 70 miles to the airport, in HV mode, with no real charging to the car during the drive, leave the car for multiple days, and find a dead 12v battery on our return. Granted, I can use our quick battery jumper to kick it on, but that shouldn't be necessary, and those discharges are not helpful to the life of the battery.