I agree that the Clarity's penchant for starting up the ICE when the battery is fully charged and regen braking occurs is frustrating and counter-intuitive. In my opinion, it's the most mysterious part of the Clarity's operation and I've been waiting for Honda to provide the definitive explanation about why it happens.
My personal theory is not shared universally on this forum (to say the least). I believe that Honda's engineers wanted to provide regen braking capability even when the battery is fully charged rather than switch to mechanical braking alone. Whereas regular ICE-powered cars can use engine braking on a long, steep decline, the Clarity cannot. So when the battery is fully charged I believe the regen power from the traction motor (operating as a generator) goes to the starter motor/generator (operating as a motor) and is used to resist the rotation of the activated ICE. The lesser Honda i-MMD hybrids don't do this. Instead, they use the excess energy from the traction motor to power the starter motor/generator to turn the ICE, but the ICE is NOT activated.
The only reason I can come up with for the Clarity PHEV to activate its ICE in this situation is that the Clarity's greater weight requires the additional resistance the activated ICE can provide. The shakiest part of my theory is that the starter motor/generator is operating to slow down the ICE. Nothing I've read has confirmed this idea. The power path for this mode appears in the bottom right diagram in the chart I put together last summer.