Is it better for the battery pack to charge each night when there is still about 50% of the charge remaining, or do it every other night after depleting the battery? In winter I deplete about 70% of a full charge.
Let me first explain the theory of maximizing battery life, then I'll explain why that probably isn't applicable here.
In theory, you should try to maintain an average battery charge of 50%. For example, if your daily drive uses 50% of a full charge, then you should try to charge to 75% and discharge to 25%, meaning that ideally you should hit 25% just as you return home for the night. Similarly, if you were to use let's say 70% of the battery's full capacity, then you'd want to charge to 85% and discharge to 15%. That's the theory.
The problem is, as has already been pointed out in comments above, GM has engineered the car to reserve a certain percentage of the battery capacity; a part that is not accessible to you. GM isn't going to tell you how much that is, and unfortunately the car isn't programmed to tell you if it's lost capacity over time. So, how could you know what an actual 50% charge is? You can't. All you can tell is what the car's instrument panel says is a 50% charge... but most likely isn't.
So, for practical purposes, you should charge the car whenever you return home and it's below 80% charge. If it's 80% or above, then for maximum battery life it would be best not to charge it... unless you plan a drive the next day which will test the car's EV range, in which of course you should go ahead and charge it to what the car says is "100%".
Or... as several people have already commented above, it may be best to simply plug it in every time you park it wherever the charger is, to make sure you get into the habit and don't forget. It depends on the individual. If you really can train yourself to check the charge level before plugging in every time, then never charging when it's above 80% may work for you. But if you're like most of us, the best habit would be simply to put it on the charger every time.
If you're really concerned with battery life, then drive the car gently, and don't drive with a lead foot. (If it was a different plug-in EV, I'd add "Never use DC fast charging", but so far as I can tell, the Volt isn't built to do that at all.)
Frankly, for the average driver, you shouldn't need to worry about battery life. Unless you're going to be using the car in a way that strains the battery pack more than it's designed for, it should last as long as you'd want to keep the car.
Sorry we can't give you a more definitive answer than "it depends". But the good news is that very few people have reported any problem with the Volt's battery pack. I understand a very few have reported reduced maximum power in older Volts which have been driven long distances or have otherwise been abused, and that does indicate reduced maximum capacity.
Bottom line: Odds are very high that you won't need to worry about "babying" the battery, so long as you don't abuse the car.